Browsing by Subject "Greenhouse gas"

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Biogenic Greenhouse Gas Emissions from Agriculture in Europe - Quantification and Mitigation
(2002) Freibauer, Annette; Zeddies, Jürgen
This dissertation analyses relevant potential mitigation strategies of biogenic greenhouse gases (GHGs) in the agriculture of the European Union (EU) in light of the Kyoto Protocol. It identifies where important sources and mitigation potentials are located and what uncertainty, environmental ancillary effects and costs are associated with them. Literature reviews are performed and methodologies for environmental assessment and GHG accounting are further developed. On this basis, GHG emissions are quantified and reduction potentials are assessed at European level. In 1995, European agriculture emitted 0.84 ± 0.29 Tg N2O, 8.1 ± 1.9 Tg methane (CH4) and 39 Tg ± 25 carbon dioxide (CO2), which adds up to 470 ± 80 Tg CO2-equivalents or 11% of the overall anthropogenic greenhouse gas emissions of the EU. The detailed methodology developed here adequately resolves regional specifics of agricultural conditions and reduces the methodological uncertainty in the estimates to half of the one in the official national inventories. European agricultural soils will at maximum sequester carbon in the order of 100 Tg a-1 CO2 over the coming years, which may also provide other environmental benefits. The biological potential of bioenergy in the EU allows to substitute for 400 to 800 Tg a-1 CO2-equivalents. From an environmental perspective, the use of perennials, especially of residues and woody biomass, is preferable to intensively grown annual crops. The biological potential for technical GHG reduction measures in EU agriculture is between 100 and 200 Tg a-1 CO2-equivalents. Promising measures promote the extensivation of arable cropping by reducing nitrogen inputs, technological innovation in animal husbandry, which is best accompanied by a further decline in animal numbers, as well as rewetting drained organic soils. Most measures will provide ancillary environmental benefits. Changing the socio-economic and political frame conditions may enhance the GHG mitigation potential.
Gaseous N emissions from a loamy soil as affected by N fertilization strategies, and by the use of nitrification and urease inhibitors - Results from field and incubation experiments
(2023) Guzman Bustamante, Ivan; Müller, Torsten
Agricultural activities are responsible for a substantial share of anthropogenic greenhouse gases. At the same time, agricultural production must feed a growing world population under a changing climate. In the case of wheat, the use of nitrogen (N) fertilizers is needed in order to insure grain yield and quality. Nevertheless, its use is associated with reactive N losses, which are detrimental for the environment and human health. Among the gaseous N species emitted after N fertilization we find nitrous oxide (N2O), a potent greenhouse gas, and ammonia (NH3) that after its deposition can be oxidized to N2O. Chemical compounds such as nitrification and urease inhibitors (NIs and UIs, respectively) are a useful tool, able to raise the fertilizer nitrogen use efficiency, by retarding the nitrification of ammonium based fertilizer in the case of NIs and by retarding the hydrolysis of urea in the case of UIs. A side benefit of the use of NIs is the reduction of N2O emissions. The use of UIs reduces the NH3 volatilization. One of the most used NIs in Europe is 3,4-dimethylpyrazol phosphate (DMPP) which can be applied with ammonium sulfate nitrate (ASN). The relatively new NI, 3,4-dimethylpyrazol succinic acid (DMPSA), acts similarly to DMPP but has a different time of action and can be applied to several fertilizers, unlike DMPP. N-(n-butyl) thiophosphoric triamide (NBPT) is an effective UI that provenly reduces NH3 volatilization by inhibiting the urease enzyme. In a two-year field experiment with winter wheat several fertilizer strategies were tested, including splitting strategies, use of NIs and reduction of N amount. Reducing N amount reduces the amount of soil mineral N, which is the substrate for N2O producing microbiological processes, nitrification and denitrification. Splitting of N fertilizer might reduce soil mineral N as well because N fertilizer applications are better suited to the physiological needs of the wheat plants. Applying NIs in splitting schemes may further mitigate emissions. The relationship between N amount and N2O losses in a wheat production system was investigated by applying lower and higher N amounts than the recommended N application rate. Use of DMPP was able to reduce N2O emissions in both years, not only on an annual basis (by 21 %: 3.1 vs 2.5 kg N2O-N ha-1 a-1 average for both years) but also during winter, when up to 18 % of total annual emissions occurred. A change of the soil microbial community due to DMPP could be the reason for the reduction of winter emissions 8 to 12 months after DMPP application. An economic assessment of N fertilizer amount showed that DMPP applied with suboptimal N fertilizer amounts can maintain yield and at the same time decrease yield scaled N2O emissions compared to an optimal N fertilizer rate without NI. Using CAN together with the NI DMPSA reduced N2O emissions only during the vegetation period. On an annual basis, DMPSA did not significantly reduce N2O emissions. Because DMPSA and DMPP were applied with different N fertilizers with different ammonium and nitrate shares, a direct comparison between these two NIs cannot be made. A traditional threefold split fertilization did not reduce annual emissions compared to a single application of ASN or CAN. Nevertheless, the use of DMPP in twofold split applications reduced annual emissions significantly by 33 % and increased protein content by 1.6 %. Because N2O flux peaks were not as high as expected after N fertilization during the first year, a short experiment investigating the effect of soil moisture, N and C application on N2O fluxes was conducted. A C limitation of the field was found, which explained high N2O emission events when C was available, e.g. after rewetting of dry soil and incorporation of straw after harvest. In this context we tested the removal of wheat straw – which should reduce the organic substrate supply for denitrifiers – as a possible mitigation strategy. Nevertheless, the removal of straw had no effect on N2O emissions. Furthermore, the effect of DMPP on microorganisms was studied in an incubation experiment: the copy number of bacterial amoA genes (nitrifiers) was lowered by the use of DMPP, while the number of archaeal amoA genes was increased by DMPP. Gene copy number of denitrifiers was unaffected by DMPP, nevertheless, soil respiration was reduced when DMPP was applied. It seems as DMPP has an inhibiting effect on heterotrophic organisms, nevertheless, the investigated variables did not support this hypothesis, so that further investigation is needed. The effect of NBPT and straw residues on NH3 and N2O emissions was studied in a two-week incubation experiment with a slightly alkaline soil. NBPT reduced NH3 volatilization and N2O fluxes from urea fertilization almost completely. Incorporation of straw residues significantly increased N2O emissions. In a further four-week incubation experiment, the effect of NBPT in two concentrations and DMPP was studied. A higher NBPT concentration as the recommended rate, reduced NH3 emissions by 53 %; DMPP on the other hand increased NH3 volatilization by 70 %. Regarding N2O, DMPP reduced emissions to the same level as the unfertilized control; NBPT only shifted the emission peak so that by the end of the experiment no difference in the cumulative N2O emission was found between urea and NBPT treatments. These results show that UI can lead to a reduction of N2O emissions, but the ammonium formed by the urea hydrolysis should be used by crops, otherwise it serves as a substrate for N2O production in soils. In the final incubation experiment, the combined application of a NI (DMPSA) and a UI (NBPT) was studied. Lower concentrations than the recommended doses were applied in order to assess synergistic effects. The combined application of DMPSA and NBPT did not lead to synergistic effects in the analyzed variables (soil urea amount, soil mineral N, ammonia volatilization, soil respiration and N2O emission). The higher the NBPT concentration, the slower urea was hydrolyzed and the higher the reduction in NH3 volatilization. A third of DMPSA application rate was enough to reduce N2O emissions; however, the use of NI increased NH3 losses. Our results highlight the importance of annual datasets when assessing mitigation strategies for N2O. For wheat production, a reduction of the N fertilizer amount when a NI is used should be taken into consideration. When elite wheat cultivars are grown split application with NI fertilizers could ensure high protein content and simultaneously reduce N2O emission. Urea fertilizer should be applied with NI and UI so that NH3 volatilization and N2O emission is reduced. Nevertheless, long-term effects of these compounds on soil microbiology must be monitored to avoid unseen ecotoxicological effects. Since some of these compounds or their metabolites might be absorbed by plants and end up in food and feed more research is needed to protect consumers.
Greenhouse gas emissions from rice production in the Vietnamese Mekong River Delta as affected by varietal selection and water management
(2023) Vo, Thi Bach Thuong; Asch, Folkard
The topic of this dissertation deals with rice production, the predominant source of daily nourishment for more than half of the worlds population. Rice production is directly affected by global climate change through aggravating climatic conditions, but is also one of the major sources of greenhouse gases (GHG) in the agricultural sector. The latter aspect is investigated in 4 publications by assessing the factors contributing to emissions, the quantification of GHG emissions across different scales, and possible mitigation of GHG emissions. In totality, these studies aim at bridging the gap between field measurements to national extrapolations in view of both GHG inventories and future mitigation programs. In terms of methodologies, the publications compiled in the following chapters represent a broad spectrum ranging from field measurements to meta-analysis, but they all deal with the emission of methane (CH4) which is generated in rice fields due to the unique feature of ‘semi-aquatic’ soils. The publications based on newly conducted field measurements also a nitrous oxide (N2O) which is a potent GHG emitted typically emitted from rice fields in low quantities. Chapter 2 (Vo et al. 2018) compiles field measurements from the Vietnamese Mekong River Delta (MRD) which accounts for more than 50% of the country’s rice production. Emission factors (EFs) are used to estimate total emissions associated with the area of rice production. The Intergovernmental Panel on Climate Change (IPCC) has given the default EFs that are based on global averages as Tier 1 approach. However, the IPCC guidelines encourage national reporting institutions to conduct field measurements of GHG emissions and to determine country-specific EFs as the basis of the Tier 2 approach. Tier 2 further accounts for the fact that emissions may also be highly variable within a given country by requesting for disaggregation of EF at a sub-national scale. Therefore, the most recent GHG inventories for Vietnam are based on region-specific EFs under the IPCC Tier 2 approach, which is implemented using national activity data (i.e., national average cultivation period of rice and harvested area). In Chapter 2, we developed the specific EFs for different hydrological sub-zones and growing seasons in the MRD to achieve disaggregated EFs that could be used for the National Communications submitted to the United Nations Framework Convention on Climate Change (UNFCCC). Due to the distinct bio-physical condition and cropping cycle, the results show the lowest emissions in the saline sub-zone. While alluvial, acid sulfate soils had intermediate levels, the highest emissions were found in the deep flood sub-zone. In Chapter 3 (Vo e al. 2018), we expanded the geographical scope of the GHG assessment to the entire country. This meta-analysis of CH4 data covers 73 cropping seasons at 36 field sites across the rice-growing areas of Vietnam under the IPCC’s baseline conditions (i.e., continuously flooded, no organic amendments) in the three main cropping seasons. As an output of this study, a structured database contained the location and season of each measurement as well as site-specific bio-physical factors and crop management at the site scale. In the next step, we developed disaggregated EFs for different zones and cropping seasons across the country that can be used for future reporting commitments of Vietnam as part of a more accurate Tier 2 assessment. The calculated EFs were generally higher than the IPCC defaults and the values used for Vietnam’s 3rd National Communications for the North, Central, and South Vietnam. Chapter 4 (Vo et al. 2023) has to be seen in the context of Vietnam’s climate change policy that aims at reducing GHG emissions from rice production. Mitigation in rice production will be crucial for Vietnam because CH4 from rice accounts for about 15 % of the national GHG which is more than the entire transport sector even without considering CO2 and N2O emissions along the rice value chain. Previous studies have assessed the potential practices by changes in farming practices, namely water, nutrient, and straw management, and almost uniformly concluded that Alternate Wetting and Drying (AWD) is the most promising strategy for achieving a sizable mitigation of GHG emissions. Given the intense rainy season in southeast Asia, however, the precipitation is often too high to implement this water regime and will not provide any economic benefit from water saving. In turn, it is important to consider other mitigation strategies such as the selection of low-emitting cultivars. We conducted a field screening of 20 rice varieties that was expanded by assessing the interactive effect of variety selection and AWD. An experimental layout with 120 plots (based on 3 replicates) was required to assess this interaction of variety and water management in the field using the closed chamber method to collect air samples followed by lab analysis (using a gas chromatograph) to quantify the CH4 and N2O concentrations. The results of this study confirmed that GHG emissions from rice fields are dominated by CH4 emissions whereas N2O emissions were negligible. Compared with IPCC default values, the data set from two dry seasons yielded higher emissions under a baseline of continuous flooding (EF = 2.96 kg CH4 ha-1 d-1) and lower Scaling Factors (SF) of AWD (SF = 0.4). Chapter 5 (Asch et al. 2023) deals with the agronomic aspects of both AWD and variety selection and their implications on the economic viability of future mitigation efforts. While AWD is more efficient in reducing CH4 emissions than variety selection, this water management practice resulted in a slight yield decrease in our field study. Given the limited applicability of AWD, the selection of varieties is a much more adaptable approach and is also beneficial in terms of farmers’ adoption because it does not require any crop management changes. However, this strategy could also impact profits since the lowest-emitting variety may not have the highest rice yields. In the context of future mitigation programs in the MRD, the dry season allows good control of the water table, so AWD should be the core of any mitigation effort. Variety selection on the other hand should be targeted in those seasons and locations that do not allow draining the fields. In turn, low-emitting varieties should become an integral part of future mitigation programs to supplement AWD within a systematic out scaling. In terms of economic trade-offs for the farmers, we assumed a scenario with compensation derived from the still premature carbon markets. The potential profit increments are very low and not attractive if distributed to farmers directly, but may collectively be used for investments in rural development by government agencies for benefitting farmers indirectly, e.g. by improving the irrigation infrastructure.
Nachhaltige Biogasproduktion unter besonderer Berücksichtigung des Einsatzes von Zuckerrüben und Grünlandaufwuchs sowie der Gärrestverwertung
(2017) Auburger, Sebastian; Bahrs, Enno
The present cumulative dissertation assesses the sustainability of biogas production in Germany from different points of view. A special focus is brought to sugar beets and grassland as a biogas feedstock as well as to biogas residue utilization. Chapter 2 presents an approach of manure distribution within regions based on municipality biogas and livestock production data. The developed algorithm distributes nutrients of nutrient surplus municipalities to municipalities with nutrient adsorption capacity within a study area (Lower Saxonia and North Rhine-Westphalia). It was shown that farmers and biogas producers will be confronted with higher manure and biogas digestate disposal costs. Chapter 3 enlarges the view by taking pig producers and experts interviews into consideration. Chapter 4 presents an approach to determine the regional biogas feedstock input based on regional agricultural production cost data and almost 8,000 biogas plants in Germany. By using a linear optimization approach regional feedstock inputs are calculated. Furthermore greenhouse gas emissions of power production based on biogas are estimated. Chapter 5 enlarges the modeling approach by an energy balancing tool and assesses sugar beets as an energy crop for biogas production in detail. Therefore different scenarios are taken into account. Silage corn was the most competitive feedstock over almost every region in Germany. Round about 160 kg CO2eq per kWh from biogas production were calculated, which is a significant lower value in comparison to greenhouse gas emissions from current power mix in Germany. Chapter 6 focuses on grassland as a biogas feedstock. Based on data availability calculation had to be restricted to Federal States of Schleswig-Holstein, Lower Saxonia and Bavaria. Results show that grassland is a competitive biogas feedstock in regions, which are characterized by unfavorable production circumstances of silage corn and only if for grassland favorable scenario assumptions are chosen.