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Untersuchungen zur Aufbereitung und Umwandlung von Energiepflanzen in Biogas und Bioethanol
(2008) Schumacher, Britt; Jungbluth, Thomas
Due to finite fossil resources, one opportunity for the future is to increase the supply of energy out of renewable energy sources. One of many opportunities is the use of biomass, which offers plenty combinations of different kinds of biomass, paths of utilization and conversion techniques for a flexible adaptation to natural local and regional frameworks as well as the anthropogenic needs. For an efficient utilization of the limited arable land for the supply of bioenergy, there is a need of up-to-date and proof data about specific energy yields and yields per hectare. The aim of this investigation was to determine these data for the biogas and bioethanol sectors. Batch-tests were carried out in laboratory scaled digesters to investigate specific biogas and bioethanol yields. Additionally the testing of different techniques of pre-treatment for energy crops and their effects on the biogas yield and the progression of the formation of methane were focused. The conversion of maize silage and full ripe triticale into biogas and bioethanol was compared by an energy and environmental balance. The steam explosion technique was included. Pre-treatment The steam explosion pre-treatment of biomass increases the speed of formation of methane and partly increases the methane yields. The effects differ depending on the kind of biomass and the stage of ripening. Other techniques of pre-treatment like microwaving and cooking did not show significant or partly negative effects. A variation of parameters in the trial setup might be interesting. Besides the positive effects of the steam explosion technique there are some arguments like the additional costs of investment, the diminished concentration of nutrients respectively the increase of material flow against it. The additional energy consumption, mostly thermal energy, can be supplied from waste heat out of the combined heat and power plant (CHP). The screening and the production of technical enzymes for the efficient pre-degradation of raw materials containing high amounts of lignocellulose should be the subject of research and development in the future. The combination of biological (enzymatic), chemical, thermal and mechanical pre-treatment techniques need to be investigated with the focus on energy efficiency. Methane yields of energy crops and stillage A broad number of biogas tests had been carried out on various maize cultivars. The specific methane yields of the maize cultivars varied over the harvesting date differently. The cultivars with a low ripening number reached higher specific methane yields. The dominant factor for the energy yield per hectare was the dry matter yield, not the specific methane yield. In general it is recommended to use well adapted cultivars with high dry matter yields and a good ensilaging behaviour. The catch crops increased the methane yields per hectare just partly. But for reasons of soil conservation the cultivation is recommended. The nitrogen fertilizer had mostly a positive effect on the dry matter yields and the energy yields per hectare, respectively. Maize gained higher energy yields per hectare than switch grass. The utilization of stillage out of whole maize plants or triticale´s grain from the ethanol production as well as the utilization of by-products like straw in the biogas production could double the energy output per hectare compared to the simple ethanol production. Further options for the optimization of the biogas production under conditions of practice are digester systems well-adapted on the substrate, the use of multi step systems and the development of analytic methods in order to gain effective process control. Correlation between chemical components and measured methane yields The specific methane yields calculated out of the neutral detergents fibre, starch, sugar, raw proteins and its substrate-specific factors were very close to the experimentally determined yields of the maize cultivars for the four harvesting times. But the measured and calculated values showed no correlation. Whether the biogas tests can be replaced, by other methods or techniques of analysis of the components and the determination of additional components for the estimation of the potential of new cultivars, should be subject of further investigations. Bioethanol yields The energy yields on the conversion pathway bioethanol without using the by-products are lower than the yields via conversion into biogas, because the ethanol fermentation is limited on material that can be converted into sugar first. The advantage of the ethanol production is a fluid fuel as result of the process. Combining the ethanol production with a biogas plant, the by-products also can be used energetically and a gaseous energy carrier can be produced. There are high potentials for the bioprocess engineering, for instance in breeding of microorganisms for the degradation of lignocellulosic biomass or of C5-sugar. Furthermore a process optimization of water and energy input is recommended. Energy and environmental balance Biogas as well as bioethanol (combined with biogas) is able to reduce the consumption of non-renewable energy carrier and its emission under the investigated scenarios and the scoop set. A future task will be the development of differentiated and well-adapted concepts on the basis of a decision between (liquid) fuels or stationary supply of thermal and electrical energy out of biomass. The aim is an efficient use of the limited areas of arable land and forests for the supply with bioenergy carriers by a useful combination of biomass, paths of utilization and conversion technique depending on natural local and regional conditions as well as the anthropogenic needs.